From Molecules to Materials Pathways to Artificial Photosynthesis

This interdisciplinary book focuses on the various aspects transformation of the energy from sunlight into the chemical bonds of a fuel, known as the artificial photosynthesis, and addresses the emergent challenges connected with growing societal demands

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m Molecules to Materials Pathways to Artificial Photosynthesis

From Molecules to Materials

Elena A. Rozhkova • Katsuhiko Ariga Editors

From Molecules to Materials Pathways to Artificial Photosynthesis

Editors Elena A. Rozhkova Center for Nanoscale Materials Argonne National Laboratory Argonne, IL, USA

Katsuhiko Ariga Supermolecules Unit, Research Center for Materials Nanoarchitectonics National Institute for Materials Science Tsukuba, Ibaraki, Japan

ISBN 978-3-319-13799-5 ISBN 978-3-319-13800-8 DOI 10.1007/978-3-319-13800-8

(eBook)

Library of Congress Control Number: 2015933813 Springer Cham Heidelberg New York Dordrecht London © Springer International Publishing Switzerland 2015 This work is subject to copyright. All rights are reserved by the Publisher, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission or information storage and retrieval, electronic adaptation, computer software, or by similar or dissimilar methodology now known or hereafter developed. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. The publisher, the authors and the editors are safe to assume that the advice and information in this book are believed to be true and accurate at the date of publication. Neither the publisher nor the authors or the editors give a warranty, express or implied, with respect to the material contained herein or for any errors or omissions that may have been made. Printed on acid-free paper Springer International Publishing AG Switzerland is part of Springer Science+Business Media (www.springer.com)

Preface

This multifaceted book focuses on the various aspects of artificial photosynthesis that replicates the natural processes of capturing, conversion, and storage of solar energy. Assisted by photocatalysts, artificial photosynthetic schemes allow the direct transformation of sunlight, an infinite energy source, into energy-rich chemical compounds, mostly hydrogen and organic molecules. Motivated by exponentially growing societal demands for clean energy within the last decade, artificial photosynthesis became a multidisciplinary consortium that combines efforts of biologists, chemists, materials scientists, and engineers. Artificial photosynthesis field spans from the understanding of fundamental biological principles of sunlight capturing and splitting of water toward engineered functioning devices. The introduction of nanoscience, nanotechnology, and nanoscale materials gives an additional thrust to the field. The final goal of such multidimensional efforts is to engineer advanced materials with tunable photophysical properties capable of converting solar energy to chemical fuels having high perfor