HAP Coatings for Biomedical Applications: Biocompatibility and Surface Protection Against Corrosion of Ti, Ti6Al4V and A
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HYSICOCHEMICAL PROBLEMS OF MATERIALS PROTECTION
HAP Coatings for Biomedical Applications: Biocompatibility and Surface Protection Against Corrosion of Ti, Ti6Al4V and AISI 316L SS Aysel Büyüksağişa, * and Nihal Çiftçia aAfyon
Kocatepe University, Science and Art Faculty, Chemistry Department, Afyonkarahisar Turkey *e-mail: [email protected] Received August 22, 2019; revised November 23, 2019; accepted March 15, 2020
Abstract—The implants used as cardio stents, orthopedic and dental implant may be subjected to biological corrosion. Uncoated implants can be corroded in various parts of the body due to acidic erosion and oxidation. This paper presents the findings of a coating technique for the deposition of hydroxyapatite (HAP) coatings on Ti, Ti6Al4V and AISI 316L stainless steel substrates (316L SS). HAP synthesized using the sol–gel technique have been successfully produced. The corrosion behaviors of uncoated and HAP coated substrates were investigated in Ringer’s and 0.9% NaCl solutions. The HAP coatings obtained by the sol gel method are effective in preventing corrosion and increased the polarization resistance values compared to the uncoated samples. Surface structures and chemical composition of the coatings were investigated by scanning electron microscopy (SEM) and energy diffraction X-ray (EDX) methods. SEM images of HAP coated substrates show cauliflower-like structures on the surface. Furthermore, the HAP coatings formed do not completely cover the surface. EDX analysis of HAP coated substrats were determined that there were Ca, O and P as well as oxides on the surface. The obtained HAP powder was characterized by X-ray diffraction (XRD) and Fourier transform infrared (FTIR) methods. In XRD analysis, it was analysed that HAP powder consisted of CaP and HAP structures. In addition, FTIR spectrum was determined that characteristic HAP absorption bands. Keywords: Sol–gel, hydroxyapatite, corrosion, Ti implants, AISI 316L SS DOI: 10.1134/S2070205120040085
1. INTRODUCTION Biomaterials are classified into three basic classifications: metals, ceramics and polymers. Biomaterials should be safe, renewable, economic, psychological and aesthetically acceptable [1]. Metallic implants are 316L SS, Co–Cr alloys, Ti and its alloys that can be used to fix and transport broken load-bearing. However, osseointegration between a metal and a bone in the human body are difficult [2, 3]. Therefore, metal surfaces are coated with calcium phosphate coatings that are biologically similar to bone structure [4]. HAP and other calcium phosphates such as α- or β-tricalcium phosphates (α- or β-TCP, Ca3(PO4)2) are considered to have excellent biocompatibility. Furthermore, each of phosphate thickness not only provides little effect on the composition of the coating, but also pH and reaction diversity. Some of the CaP compositions such as α-TCP and tetracalcium phosphate (TTCP) can become hard polymer particles in aqueous solution and can be used as bone cement materials [5]. HAP has preference because of its excellent biocompatibil
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