Heat and cold storage with PCM An up to date introduction into basic

Latent heat storage with phase change materials (PCM) has the potential to improve significantly the efficiency of heat and cold storages and to reduce their size considerably. The book is an introduction into the field for researchers and students. It su

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Other common units units

A

m2

area

C

J/kg⋅K, J/m3⋅K, J/mole⋅K

heat capacity

c

C/mass, …

specific heat capacity per mass, per volume, or per amount

CR

mg/m2yr

corrosion rate

d

m

thickness

H

J

enthalpy

h

J/kg, J/m3, J/mol

specific enthalpy per mass, per volume, or per amount

k

W/m2K

overall heat transfer coefficient

m

kg

mass

mol

mol

f

fraction of mass, volume, or amount

amount of matter / number of molecules

n

integer number

P

J/s = W

kW

p

Pa

bar (=105 Pa) pressure

Q

J

kWh

dQ/dt W (=J/s) dV/dt m3/s

power heat heat flux

liters/s

volume flow rate

dq/dt

W/m2

heat flux density

r, R

m

radius

Rth

K/W

thermal resistance

S

J/K

entropy

s

m

location of the phase front

T

°C

temperature

ΔT

K

temperature difference

+

dimensionless ratio of radiuses

s

t

s

U

J

min, hour

time

u

m/s

V

m3

x,y,z

m

Cartesian space coordinates

α

W/m2K

convective heat transfer coefficient

internal energy flow speed liter (=10-3 m3) volume

(Continued)

298

10 Appendix

Table 10.1. (Continued) Si-units

α

m2/s

β

K/s

Other common units units thermal diffusivity K/min

heating rate

β

dimensionless ratio of thermal resistances

η

N⋅s/m2

λ

W/mK

thermal conductivity

ρ

kg/m3

density

viscosity

Because of the frequent use of h as enthalpy, it would be confusing using also h as convective heat transfer coefficient. To avoid confusion, a different notation described in the following table is used throughout the book to describe heat transfer. Generally, the heat flux dQ/dt and the heat flux density dq/dt are related by dQ/dt = A ⋅ dq/dt. Table 10.2. Notation for heat transfer. effect

sketch

Heat transT fer dQ/dt through an area A by conduction ΔT

Notation often used

Notation here

dQ / dt = Q&

dQ / dt = Q&

= A⋅ k ⋅

ΔT Δx

= A⋅λ ⋅

ΔT Δx

k = thermal conductivity

λ = thermal conductivity

dQ / dt = Q&

dQ / dt = Q&

x Δx Heat transfer dQ/dt from an area A by convection

T

= A ⋅ hconv ⋅ ΔT

= A ⋅ α ⋅ ΔT

hconv = convection heat transfer α = convection heat transfer coefficient coefficient

ΔT x

10 Appendix

effect

Notation often used

sketch

Overall T heat transfer dQ/dt through an area A, for ΔT example by convection on the surface and conduction inside

dQ / dt = Q&

299

Notation here

dQ / dt = Q&

= A ⋅ U ⋅ ΔT = A ⋅ k ⋅ ΔT 1 / U = 1 / hcond + Δx / λ 1 / k = 1 / α + Δx / λ + 1/ α + 1 / hcond x

U = overall heat transfer coef- k = overall heat transfer coefficient ficient, or just U-factor R = 1/U overall thermal resistance, or just R-value with

dQ / dt = Q& = A ⋅ 1 / R ⋅ ΔT

300

10 Appendix

Table 10.3. Subscripts a, amb ambient air

air

bp

boiling point

eff

effective

el

electric

f

fusion

i, j

integral numbers

in

ingoing

lm

logarithmic mean

max

maximum value

min

minimum value

mol

molar

mp

melting point

obj

object

out

outgoing

p

at constant pressure

pc

phase change

r

reference

s

sample

st

standard

th

thermal

V

at constant volume

wall

wall

water water Table 10.4. Superscripts. a

air

amb ambient CV

con