Hydrosilyl-Functional Polysiloxanes: Synthesis, Reactions and Applications
A comprehensive review on preparation methods of linear, branched, star and dendritic poly(hydrosiloxane)s (PHS), mainly poly(methylhydrosiloxanes) (PMHS) and Si-H functional silsesquioxanes (spherosilicates) is presented in this chapter. The most importa
- PDF / 2,252,689 Bytes
- 86 Pages / 439.37 x 666.142 pts Page_size
- 102 Downloads / 213 Views
Hydrosilyl-Functional Polysiloxanes: Synthesis, Reactions and Applications Jerzy J. Chruściel
Abstract A comprehensive review on preparation methods of linear, branched, star and dendritic poly(hydrosiloxane)s (PHS), mainly poly(methylhydrosiloxanes) (PMHS) and Si-H functional silsesquioxanes (spherosilicates) is presented in this chapter. The most important applications of PMHS in technology of silicones, modifications of different polymers and in materials science were reviewed. Keywords Hybrid silicone materials · Hydrolytic polycondensation · Hydrosilylation · Poly(methylhydrosiloxanes) (PMHS) · Ring-opening polymerization (ROP)
Abbreviations ((HMe2SiO)2SiO)3) Hexakis(dimethylsiloxy)cyclotrisiloxane ((HMe2SiO)2SiO)4 Octakis(dimethylsiloxy)cyclotetrasiloxane ((HMe2SiO)SiO1.5)8) Octakis(dimethylsiloxy)octasilsesquioxane - Q8MH8 ((Me3SiO)2SiO)4) Octakis(trimethylsiloxy)cyclotetrasiloxane (H2SiO)n (n = 4–23) Oligodihydrocyclosiloxanes (HMeSiO)5 1,3,5,7,9-pentamethylcyclopentasiloxane (Me2PhSi)2O 1,1,3,3-tetramethyl-1,3-diphenyldisiloxane (MVi)2SiMeH 1,5-divinyl-1,1,3,5,5-pentamethyltrisiloxane Ammonium sulphate (NH4)2SO4 3D Three dimensional Polymerized methylvinylbis(dimethylsiloxy)silane AB2 AB3-II Vinyltris(dimethylsiloxysilane) AB3-III Tris(vinyldimethylsiloxysilane) AB4 Methylvinylbis[methylbis(dimethylsiloxy)siloxy]silane AB6 Vinyltris(methylbis(dimethylsiloxy)siloxy)silane APTES (3-aminopropyl)triethoxysilane J. J. Chruściel (*) ŁUKASIEWICZ Research Network, Textile Research Institute, Łódź, Poland e-mail: [email protected]; [email protected] © Springer Nature Switzerland AG 2020 T. J. Gutiérrez (ed.), Reactive and Functional Polymers Volume One, https://doi.org/10.1007/978-3-030-43403-8_14
329
330
J. J. Chruściel
ATRP Atom transfer radical polymerization B(C6F5)3 Tris(pentafluorophenyl)borane B(OSiMe2Cl)3 Tris(chlorodimethylsiloxy)borane br-PMHBS Branched poly(methylhydroborosiloxane) BTC 1,3,5-benzenetricarboxylic acid C5H5N Pyridine CA Cellulose acetate Ca3Si3O9Cl6 Pseudowollastonite Pentamethylcyclotrisiloxane - (Me2SiO)2(MeHSiO) c-D2DH ClSiMe2H Chlorodimethylsilane CNF Carbon nanofiber CPA Hexachloroplatinic acid - H2PtCl6 - Speier’s catalyst D3 Hexamethylcyclotrisiloxane Octamethylcyclotetrasiloxane - (Me2SiO)4 D4 D5 Decamethylcyclopentasiloxane - (Me2SiO)5 DBSA Dodecylbenzenesulphonic acid DBTDL Dibutyltin dilaurate DCP Dicumyl peroxide DDS Dimethyldichlorosilane - Me2SiCl2 DH4 1,3,5,7-tetramethyltetrahydrocyclotetrasiloxane DH5 1,3,5,7,9-pentamethyl-1,3,5,7,9-pentahydrocyclopentasiloxane DHn Methylhydrocyclosiloxanes DMAP 4-(N,N-dimethylamino)pyridine DMCS Chlorodimethylsilane - HMe2SiCl Cyclic dimethylsiloxane-co-methylhydrosiloxane DmDHn DMF N,N-dimethylformamide Dn, n ≥ 3 Dimethylcyclosiloxanes DSC Differential scanning calorimetry DVB 1,4-divinylbenzene DVi4 1,3,5,7-tetramethyl-1,3,5,7-tetravinylcycletetrasiloxane - (MeViSiO)4 Et3B Triethylborane Et3N Triethylamine Et3SiH Triethylsilane FR Flame retardants FRs Fire retardants FTIR Fourier transform infrared H2SiCl2 Dichlorosilane
Data Loading...
