Insights into the Adsorption Behavior of a Prototype Functional Molecule

Michael Lepper presents a detailed room temperature scanning tunneling microscopy study of Nickel-tetraphenyltetrabenzoporphyrin on Cu(111), a prototype system for the fabrication of functional molecular architectures. The peculiar adsorption behavior, in

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Springer awards „BestMasters“ to the best master’s theses which have been completed at renowned universities in Germany, Austria, and Switzerland. The studies received highest marks and were recommended for publication by supervisors. They address current issues from various fields of research in natural sciences, psychology, technology, and economics. The series addresses practitioners as well as scientists and, in particular, offers guidance for early stage researchers.

Michael Lepper

Insights into the Adsorption Behavior of a Prototype Functional Molecule A Scanning Tunneling Microscopy Study Foreword by PD Dr. Hubertus Marbach and Prof. Dr. Hans-Peter Steinrück

Michael Lepper Erlangen-Nuremberg, Germany

OnlinePLUS material to this book can be available on http://www.springer-imprint.de/978-3-658-11046-8 BestMasters ISBN 978-3-658-11046-8 ISBN 978-3-658-11047-5 (eBook) DOI 10.1007/978-3-658-11047-5 Library of Congress Control Number: 2015947132 Springer Spektrum © Springer Fachmedien Wiesbaden 2015 This work is subject to copyright. All rights are reserved by the Publisher, whether the whole or part of the material is concerned, speci¿cally the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on micro¿lms or in any other physical way, and transmission or information storage and retrieval, electronic adaptation, computer software, or by similar or dissimilar methodology now known or hereafter developed. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publication does not imply, even in the absence of a speci¿c statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. The publisher, the authors and the editors are safe to assume that the advice and information in this book are believed to be true and accurate at the date of publication. Neither the publisher nor the authors or the editors give a warranty, express or implied, with respect to the material contained herein or for any errors or omissions that may have been made. Printed on acid-free paper Springer Spektrum is a brand of Springer Fachmedien Wiesbaden Springer Fachmedien Wiesbaden is part of Springer Science+Business Media (www.springer.com)

Foreword

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Foreword 

With the invention of the scanning tunneling microscope (STM) in the early 80’s of the last century, the direct real space observation of atoms and molecules on extended solid surfaces became possible. Due to its unparalleled capabilities, the STM quickly established itself as a powerful tool in fundamental sciences and is nowadays a standard instrument in laboratories all over the world. The investigation of large organic molecules on surfaces by STM has become a vivid research field with the vista to engineer functional devices. Specific interactions between absorbed molecules and/or with the underlying substrate often trigger peculiar adsorption behaviors like the self-assembly into long range ordered arrays. Due to the