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Acetylides 80 Adaptive natural density partitioning 294 Alkyls 113 ligands 115 All transition metal aromaticity 275 All-metal aromatic rings 219 Anisotropy of induced current density (ACID) 222 1,8-Anthracenedicarboxylic acid 34 Antibonding 135 ArMMAr (Cr, Fe, Co) 83 Aromaticity, all transition metal 277 multifold 223, 277 Aromaticity/antiaromaticity 217 d-AO-based 298 p-AO-based 296 s-AO-based 295 electronic indicators 223 four-/five-/six-membered rings 252 Group 1 metal atoms 226 Group 2 metal atoms 226 Group 13 metal atoms 229 Group 14 metalloid/metal atoms 230 Group 15 metalloid/metal atoms 231 lanthanides/actinides (f-orbital aromaticity) 268 magnetic indicators 219 transition metals 234, 296 Aryl chromium halide 66 2,6-Azulenedicarboxylate 40 Bismuth, dibismuthenes 157 Bond length/order 123 Bond stretch isomers 6 Canonical molecular orbital (CMO) 222 Carbenoid gallium(I) 167 Carboxylate linkers 41 Catenation 190

Group 13 elements 209 Group 15 elements 207 3-Center-2-electron interaction 118 Charge resonance bands 47 Chemical bonding 277 Chromium, trichromium species 3 complexes, terphenyl ligand substituent effects 86 Clusters 277 Cobalt, tricobalt 5 Cobalt(II) terphenylmetal halide 70 Copper, organocopper(I) terphenyls 104 tricopper 10 Cyanoorganocuprate 104 Cyclooctatetraenyl terphenyl 62 Cyclopentadienyl tungsten dicarbonyl compounds 134

DFT 226 N; N 0 -Diaryloxamidate 42 Dibismuthenes 157, 158 Diborane 120 2,7-Dihyhydroxynaphthyridine 34 Dimers of dimers 30 Dinuclear compounds, double hydrogen bridges 132 quadruple hydrogen bridges 139 single hydrogen bridges 129 triple hydrogen bridges 136 Dinuclear molybdenum, bonding, bridging methyl/hydride ligands 122 Dioxalene dianions 32 Dioxolene 43 3,6-Dioxypyradizine 35 Di-2,20 -pyridylamine (Hdpa) 2

Electronic coupling 29 frontier molecular orbital interactions 37

307

308 Electronic structure 2, 3, 196 EPR spectroscopy 45 Extended metal atom chains (EMACs) 2, 12 heterometallic 23

Fe–Ga–Fe 161 Formamidinates 36, 42

Ga(I), coordination chemistry 149 ligands, NHC analogue 149 GaCp 158 complexes, zinc compounds 166 Ga(Giso) 149 Gauge including atomic orbital (GIAO) 222 Gold terphenyl 105 Group 11 elements, terphenyl derivatives 102 Group 14 elements 191

Half-arrow method 120, 128 Half-electron method 121, 128 Heterometallic compounds 1 Hume–Rothery phases 183 Hydrides, bridging ligands 113, 115

Iridium 136 Iron triple bond 137 Iron(II) terphenyl metal halide 70 IVCT 47

Ligands, axial/equatorial 14 Loops 30, 52 LX “half-arrow” electron-counting 128

M–Ga bonding, Ga(I) ligands 165 M–M bond order ambiguities 115 M(ZnR)n 168, 181 Magnetic aromaticity 219 Manganese halides, terphenyl 67 Metal atoms, rings 217 Metal(I) dimers, terphenyl stabilized 83 Metal–GaR bonding 165 Metal–metal bonds 1, 113 Metals 113 Metal-to-bridge charge transfer bands 48 Mixed valence 30 MM quadruple bonds 29 Molecular conductance measurements 21 Molecular wires 1

Index Molybdenum 29, 125 Mo(ZnH)12 172 Multifold aromaticity 223, 277 NHC (N -heterocyclic carbene) 149, 183 Nickel, tr