Octanuclear Compounds

(3-CF3C6H4)nCu8 (n = 4, 6) are formed by the thermal decomposition of (3-CF3C6H4Cu)8 (see below) in C6H6 or dioxane at 25 to 80°C. Cryoscopic measurements in C6H6, assay both for biaryls and hydrolyzable CF3C6H4 groups, direct 19F NMR observation in dioxa

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~-

iii"

f...

i.:r

C)

s i

J

4

v 48

23

73 56 30 57** 72 La 39 Hf 43 Ta 50 Ba

39 40 41 y 39 Zr 42 Nb49

22 21 Sc 39 Jj 41

58 Ce

90 -l 91 Th Pa

'**Lanthanides 39

'***Actin ides

59 Pr

u

92

60 Nd

87 88 31 89*** 104 71 105 71 Fr 25a Ra Ac 40

55 ?5 Cs ··

38 Sr 29

20 Ca 28

19 22 K

37 24 Rb

12 Mg 27

II 21 Na

Li 20 Be 26

3

I H 2

13 Al 35

5 B 13

93 Np

61 Pm

94 7 Pu

62 Sm

I!

50 sn 46

32 Ge45

14 Si 15

6

c 14

95 Am

63 Eu

96 71 Cm

64 Gd

97 Bk

65 Tb

98 Cf

66 Dy

99 Es

67 Ho

100 7 Fm

68 Er

101 Md

69 Tm

76 77 78 79 80 81 82 Os 66 lr 67 Pt 68 Au 62 Hg34 Tl 38 Pb 47

43 44 45 46 47 48 49 Tc 69 Ru 63 Rh 64 Pd 65 Ag 61 Cd 33 In 37

74 75 w 54 Re 70

42 Mo 53

24 25 26 27 28 29 30 31 Cr 52 Mn 56 Fe 59 Co 58 Ni 57 Cu 60 Zn 32 Ga 36

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Periodic Table of the Elements with the Gmelin System Numbers

g3

71 Lu

84 12 Po

52 11 Te

34 10 Se

102 71 103 7 1 No Lr

70 Yb

:~ 19

~~ 18

33 As 17

~5 16 ~6 9

7 N4

54 1 Xe

Kr

as 1

18 I Ar

10 I Ne

2 He l

I~H.''i

85 as At 8a Rn 1

513 8

35 7 Br

17 6 Cl

~5

~2

Gmelin Handbook of Inorganic Chemistry 8th Edition

Gmelin Handbook of Inorganic Chemistry 8th Edition

Gmelin Handbuch der Anorganischen Chemie Achte, voLLig neu bearbeitete Auflage

Prepared and issued by

Gmelin-lnstitut fOr Anorganische Chemie der Max-Planck-Gesellschaft zur Forderung der Wissenschaften Director: Ekkehard Fluck

Founded by

Leopold Gmelin

8th Edition

8th Edition begun under the auspices of the Deutsche Chemische Gesellschaft by A. J. Meyer

Continued by

E.H.E. Pietsch and A. Kotowski, and by Margot Becke- Goehring

Springer-Verlag Berlin Heidelberg GmbH 1987

Gmelin-lnstitut fUr Anorganische Chemie der Max-Planck-Gesellschaft zur Forderung der Wissenschaften

ADVISORY BOARD

Dr. G. Breil, Chairman (Ruhrchemie AG, Oberhausen-Holten), Prof. Dr. K. Dehnicke (PhilippsUniversitat, Marburg), Prof. Dr. N. N. Greenwood (University of Leeds), Prof. Dr. H. Grunewald (Bayer AG, Leverkusen), Prof. Dr. H. Harnisch (Hoechst AG, FrankfurUMain-Hochst), Prof. Dr. H. Noth (Universitat MOnchen), Prof. Dr. H. Offermanns (Degussa AG, FrankfurUMain), Prof. Dr. G. zu Putlitz (Universitat Heidelberg), Prof. Dr. A. Rabenau (Max-Planck-InstitutfOr Festkorperforschung, Stuttgart), Prof. Dr. A. Simon (Max-Planck-Institut fOr Festkorperforschung, Stuttgart), Prof. Dr. Dr. A. H. Staab (Prasident der Max-Planck-Gesellschaft, MOnchen), Prof. Dr. Dr. h.c. mult. G. Wilke (Max-Planck-lnstitut fUr Kohlenforschung, MOlheim/Ruhr)

DIRECTOR

DEPUTY DIRECTOR

Prof. Dr. Dr. h.c. Ekkehard Fluck

Dr. W. Lippert

CHIEF EDITORS

Dr. K.-C. Buschbeck - Dr. H. Bergmann, J. FOssel, H. Hartwig, B. Heibel, Dr. H. Katscher, Dr. R. Keirn, Dr. E. Koch, Dipl.-Phys. D. Koschel, Dr. U. KrOerke, Dr. H. K. Kugler, Dr. P. Merlet, Dr. E. Schleitzer-Rust, Dr. F. SchrOder, Dr. A. Slawisch, Dr. W. Topper

H. V. K. B.

C. Andersen, Dr. J. L. Grant, Haase, Dipl.-lng. G. Kirschstein, Rumpf, Dr. U. Trobisch, Vance

CORRESPONDENT MEMBERS OF THE SCIENTIFIC STAFF

Dr. Dr. Dr. Dr.

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