Approaches to Entropy

This is a book about thermodynamics, not history, but it adopts a semi-historical approach in order to highlight different approaches to entropy. The book does not follow a rigid temporal order of events, nor it is meant to be comprehensive. It includes s

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Approaches to Entropy

Approaches to Entropy

Jeremy R. H. Tame

Approaches to Entropy

123

Jeremy R. H. Tame Drug Design Laboratory Yokohama City University Yokohama, Japan

ISBN 978-981-13-2314-0 ISBN 978-981-13-2315-7 https://doi.org/10.1007/978-981-13-2315-7

(eBook)

Library of Congress Control Number: 2018952618 © Springer Nature Singapore Pte Ltd. 2019 This work is subject to copyright. All rights are reserved by the Publisher, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission or information storage and retrieval, electronic adaptation, computer software, or by similar or dissimilar methodology now known or hereafter developed. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. The publisher, the authors and the editors are safe to assume that the advice and information in this book are believed to be true and accurate at the date of publication. Neither the publisher nor the authors or the editors give a warranty, express or implied, with respect to the material contained herein or for any errors or omissions that may have been made. The publisher remains neutral with regard to jurisdictional claims in published maps and institutional affiliations. This Springer imprint is published by the registered company Springer Nature Singapore Pte Ltd. The registered company address is: 152 Beach Road, #21-01/04 Gateway East, Singapore 189721, Singapore

To Chris, Richard and Hazel.

Preface

In the preface to his outstanding textbook Protein Interactions [1], Gregorio Weber wrote the following: I have lived through the period of the rapid expansion of the experimental techniques of protein investigation and have thus witnessed the first steps of many subjects that are now presented to the student without reference to their beginnings. When possible I have tried to refer to the original research rather than to recent reviews of these subjects. For it is not difficult to notice that the first observations contain in their naïve exposition of facts and concepts much more than many subsequent elaborations.

James Clerk Maxwell himself wrote something rather similar [2]: It is of great advantage to the student of any subject to read the original memoirs on that subject, for science is always most completely assimilated when it is in the nascent state.

While no one today would attempt to learn calculus from Newton’s Principia, it seems to me that some of the earliest work on thermodynamics is also in some ways the most enlightening. There is much of value which seems to be lost in textbooks on the subject, especially on the ever-thorny topic of entropy. The problem with tackling the early works on thermodynamics is t