Phosphorus Compounds Advanced Tools in Catalysis and Material Scienc

Each chapter of Phosphorus Compounds: Advanced Tools in Catalysis and Material Sciences has been carefully selected by the editors in order to represent a state-of-the-art overview of how phosphorus chemistry can provide solutions in various fields of app

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Catalysis by Metal Complexes This book series covers topics of interest to a wide range of academic and industrial chemists, and biochemists. Catalysis by metal complexes plays a prominent role in many processes. Developments in analytical and synthetic techniques and instrumentation, particularly over the last 30 years, have resulted in an increasingly sophisticated understanding of catalytic processes. Industrial applications include the production of petrochemicals, fine chemicals and pharmaceuticals (particularly through asymmetric catalysis), hydrometallurgy, and wastetreatment processes. Many life processes are based on metallo-enzyme systems that catalyse redox and acid–base reactions. Catalysis by metal complexes is an exciting, fast developing and challenging interdisciplinary topic which spans and embraces the three areas of catalysis: heterogeneous, homogeneous, and metallo-enzyme. Catalysis by Metal Complexes deals with all aspects of catalysis which involve metal complexes and seeks to publish authoritative, state-of-the-art volumes which serve to document the progress being made in this interdisciplinary area of science. Series Editors Prof. Claudio Bianchini Institute of Chemistry of Organometallic Compounds of the Italian National Research Council (ICCOM-CNR) Via Madonna del Piano 10 50019 Sesto Fiorentino Italy

Prof. D. J. Cole-Hamilton School of Chemistry University of St Andrews North Haugh St Andrews KY16 9ST UK

Prof. Piet W. N. M. van Leeuwen Institute of Chemical Research of Catalonia Av. Paisos Catalans 16 43007 Tarragona Spain VOLUME 37: PHOSPHORUS COMPOUNDS: ADVANCED TOOLS IN CATALYSIS AND MATERIAL SCIENCES Volume Editors

Dr. Maurizio Peruzzini and Dr. Luca Gonsalvi ICCOM CNR, Via Madonna del Piano, 10 50019 Sesto Fiorentino Italy

Maurizio Peruzzini Luca Gonsalvi •

Editors

Phosphorus Compounds Advanced Tools in Catalysis and Material Sciences

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Editors Dr. Maurizio Peruzzini Institute of Chemistry of Organometallic Compounds of the Italian National Research Council (ICCOM-CNR) Via Madonna del Piano 10 50019 Sesto Fiorentino Italy e-mail: [email protected]

Dr. Luca Gonsalvi Institute of Chemistry of Organometallic Compounds of the Italian National Research Council (ICCOM-CNR) Via Madonna del Piano 10 50019 Sesto Fiorentino Italy e-mail: [email protected]

ISSN 0920-4652 ISBN 978-90-481-3816-6

e-ISBN 978-90-481-3817-3

DOI 10.1007/978-90-481-3817-3 Springer Dordrecht Heidelberg London New York Ó Springer Science+Business Media B.V. 2011 No part of this work may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, microfilming, recording or otherwise, without written permission from the Publisher, with the exception of any material supplied specifically for the purpose of being entered and executed on a computer system, for exclusive use by the purchaser of the work. Cover design: eStudio Calamar, Berlin/Figueres Printed on acid-