Theoretical Aspects of Heterogeneous Catalysis
Catalysis involves just about every field of scientific study. This means that a multidisciplinary approach is needed in catalytic studies. Catalysis involves breaking and forming new bonds and this requires an under standing of either adsorption by bond
- PDF / 49,978,261 Bytes
- 548 Pages / 430.87 x 649.13 pts Page_size
- 85 Downloads / 209 Views
VAN NOSTRAND REINHOLD CATALYSIS SERIES Burtron Davis, Series Editor
Metal-Support Interactions in Catalysis, Sintering, and Redispersion, edited by Scott A. Stevenson, R.T.K. Baker, J.A. Dumesic, and Eli Ruckenstein Molecular Sieves: Principles of Synthesis and Identification, R. Szostak Raman Spectroscopy for Catalysis, John M. Stencel Theoretical Aspects of Heterogeneous Catalysis, John B. Moffat Biocatalysis, edited by Daniel A. Abramowicz
THEORETICAL ASPECTS OF HETEROGENEOUS CATALYSIS John B. Moffat
Van Nostrand Reinhold Catalysis Series
~ ~
VAN NOSTRAND REINHOLD _ _ _ _ New York
Copyright © 1990 by Van Nostrand Reinhold Softcover reprint of the hardcover 1st edition 1990 Library of Congress Catalog Card Number H9-75H19
ISBN 978-94-010-9882-3 (eBook) ISBN 978-94-010-9884-7 DOI 10.1007/978-94-010-9882-3 All rights reserved. No part of this work covered by the copyright hereon may be reproduced or used in any form or by any means-graphic. electronic, or mechanical, including photocopying, recording, taping, or information storage and retrieval systemswithout written permission of the publisher.
Van Nostrand Reinhold 115 Fifth Avenue New York, New York 10003 Van Nostrand Reinhold International Company Limited II New Fetter Lane London EC4P 4EE, England Van Nostrand Reinhold 480 La Trobe Street Melbourne, Victoria 3000, Australia Nelson Canada 1120 Birchmount Road Scarborough, Ontario MIK 5G4, Canada 16 15 14 13 12 II 10 9 8 7 6 5 4 3 2 I Library of Congress Cataloging-in-Publication Data
Theoretical aspects of heterogeneous catalysis I John B. Moffat leditor]. p. cm. - (Van Nostrand Reinhold catalysis series) 1. Heterogeneous catalysis. QD505.T47 1990 541.3 '95--dc20
I. Moffat, John B.
II. Series.
H9-75819 CIP
Contents
Series Introduction Preface Contributors 1
A Theoretical View and Approach to the Physics and Chemistry of Zeolites and Molecular Sieves E.G. Derouane, 1.M. Andre, L. Leherte, P. Galet, D. Vanderueken, D.P. Vercallteren, and 1.G. Fripiat
Introduction Quantum Mechanical Description of AI-Site-Related Properties in Zeolites Statistical Mechanics and Molecular Dynamics Simulations Applied to a Water-Ferrierite System 2
Conceptual Background for the Conversion of Hydrocarbons on Heterogeneous Acid Catalysts 1.A. Martens and P.A. Jacobs
Introduction Nomenclature and Representation of Alkylcarbenium and Alkylcarbonium Ions Relevant to Alkane Conversion Relative Stabilities of Alkylcarbenium and Alkylcarbonium Ions Rearrangements of Acyclic Alkylcarbenium Ions in Superacids Alkylcarbenium Ions on the Surface of Heterogeneous Catalysts Carbocation Chemistry and Bifunctional Conversion of Short-Chain Alkanes Carbocation Chemistry and Bifunctional Conversion of Long-Chain Alkanes General Conclusions
IX XI
xiii 1
2 22 52
52 53 56 57 66 70 71 106 v
CONTENTS
vi
3 The Role of Next Nearest Neighbors in Zeolite Acidity and Activity William A. Wachter
110
Introduction The Aluminosilicate Active Site Buffered Behavior and Zeolite Structure Stability Criteria and the Next-Nearest-Neighb
