A comprehensive review on synthesis, characterization, and applications of polydimethylsiloxane and copolymers

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REVIEW ARTICLE

A comprehensive review on synthesis, characterization, and applications of polydimethylsiloxane and copolymers Qaiser Zaman1 · Khalid Mahmood Zia2 · Mohammad Zuber2 · Yahia Nasser Mabkhot3 · Faisal Almalki4 · Taibi Ben Hadda4,5 Received: 3 January 2019 / Accepted: 2 December 2019 © Central Institute of Plastics Engineering & Technology 2019

Abstract Polydimethylsiloxane belongs to a polymeric organosilicon compounds that is widely used as silicon-based organic polymer. Polydimethylsiloxane is a basically optically clear, inert, nontoxic and inflammable material which is widely used in medical devices, as an elastomer, antifoaming agent, heat-resistant lubricants, fire retardants, in cosmetics and for other valuable domestic applications. This comprehensive review of polydimethylsiloxane describes synthesis, characterization, surface modifications and formation of vital biodegradable films/membranes that can facilitate improvements in modern research. Polydimethylsiloxane is viscoelastic, hydrophobic, cytocompatible and herbicidal penetrant that provides water-repellent coatings in textile industry. In this study, copolymers of polydimethylsiloxane were thoroughly studied based on polyimides, carboxyesters, hydroxyethyleneoxide, degradation with polystyrene, cross-linking with block copolymers, phosphorus-based, gelatin-based and polyurethanes, which can be used for modern manufacturing purposes in all kinds of industrial world.

* Qaiser Zaman [email protected] * Yahia Nasser Mabkhot [email protected] * Taibi Ben Hadda [email protected] 1



Qarshi Industries (Pvt.) Limited, Hattar, Khyber Pakhtunkhwa, Pakistan

2



Institute of Chemistry, Government College University, Faisalabad, Pakistan

3

Department of Pharmaceutical Chemistry, College of Pharmacy, King Khalid University, Abha, Saudi Arabia

4

Department of Pharmaceutical Chemistry, Faculty of Pharmacy, Umm Al-Qura University, Mecca, Saudi Arabia

5

Laboratoire Chimie Matériaux, FSO, Université Mohammed 1ER, 60000 Oujda, Morocco



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Vol.:(0123456789)



International Journal of Plastics Technology

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PDMSg-PEO-COOH Keywords  Polydimethylsiloxane · Synthesis and characterization · Surface modification · Copolymer applications Abbreviations (PDMSX) Polydimethylsiloxane H-(PDMSX)  α-Hydridepolydimethylsiloxane (PDMSX)-TES  α-Triethoxysililpolydimethylsiloxane D4 Octamethylcyclotetrasiloxane (PDMSX)-AGE  α-Glycidoxypropilpolydimethylsiloxane APTES  α-Triethoxysililpolydimethylsiloxane HMDS 1,1,1,3,3,3-Hexamethyl-disiloxane A-PEO-TS Alpha-allyl-ω-trimethylsilylpolyethyleneoxide

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(PDMSX)g-PEO-OH Polydimethylsiloxane-ghydroxy-functionalized polyethylene oxide (PDMSX)g-PEO-COOH Polydimethylsiloxane-g-carboxyester-polyethyleneoxide IPDI Isophorone diisocyanate BDO 1,4-Butanediol (B