Determination of Pesticide Residues in Golden Berry ( Physalis peruviana L . ) by Modified QuEChERS Method and Ultra-Hig
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Determination of Pesticide Residues in Golden Berry (Physalis peruviana L.) by Modified QuEChERS Method and Ultra-High Performance Liquid Chromatography-Tandem Quadrupole Mass Spectrometry Natalia Cadavid Muñoz 1 & Luana Floriano 1 & Maiara P. de Souza 1 & Nelson M. G. Bandeira 1 & Osmar D. Prestes 1 & Renato Zanella 1
Received: 9 February 2016 / Accepted: 17 June 2016 # Springer Science+Business Media New York 2016
Abstract A fast and effective multiresidue method for the determination of 42 pesticides in golden berry was developed and validated. A modified QuEChERS method was established for sample preparation followed by ultra-high performance liquid chromatographic-tandem mass spectrometry (UHPLC-MS/MS) determination with electrospray ionization in a triple quadrupole system. Validation results were satisfactory, since the method presented recoveries between 70 and 114 % with relative standard deviations (RSD) 99 (8) 733 > 142 (59) 322 > 290 (20) 528 > 203 (22) 409 > 145 (40) 747 > 142 (53) 360 > 268 (18)
202 > 145 (28) 145 > 85 (8) 303 > 145 (20) 318 > 261 (8) 404 > 372 (30) 331 > 99 (24) 369 > 149 (18) 294 > 197 (20) 289 > 125 (18) 296 > 70 (10) 302 > 55 (38) 243 > 131 (31) 226 > 93 (33) 304 > 217 (36) 353 > 297 (20) 216 > 174 (18) 284 > 159 (16) 308 > 125 (22) 326 > 148 (34) 305 > 169 (35) 392 > 331 (18) 388 > 194 (25) 327 > 215 (37)
192 > 160 (28) 256 > 209 (20) 230 > 199 (20) 199 > 128 (18) 239 > 182 (21) 222 > 165 (16)
189 > 102 (17) 237 > 90 (10)
Quantification
338 > 70 (16) 733 > 98 (31) 322 > 125 (16) 528 > 150 (40) 409 > 186 (16) 747 > 98 (31) 360 > 164 (12)
202 > 117 (22) 145 > 73 (14) 303 > 85 (10) 318 > 160 (8) 404 > 329 (15) 331 > 127 (12) 369 > 313 (8) 294 > 69 (15) 289 > 70 (15) 296 > 99 (15) 302 > 97 (22) 243 > 97 (20) 226 > 108 (25) 304 > 202 (24) 353 > 133 (8) 216 > 96 (23) 284 > 70 (34) 308 > 125 (40) 326 > 91 (20) 305 > 97 (22) 392 > 238 (8) 388 > 163 (12) 327 > 152 (28)
192 > 132 (18) 256 > 175 (15) 230 > 125 (10) 199 > 111 (8) 239 > 72 (16) 222 > 123 (16)
189 > 144 (12) 237 > 72 (10)
Confirmation
36 8 88 39 68 5 60
27 10 41 77 51 82 67 37 78 17 17 52 88 54 81 26 41 27 26 59 63 74 78
17 86 83 43 92 62
20 70
0.9905 0.9993 0.9988 0.9996 0.9985 0.9981 0.9986
0.9998 0.9987 0.9989 0.9980 0.9983 0.9966 0.9985 0.9975 0.9978 0.9981 0.9988 0.9988 0.9992 0.9987 0.9980 – 0.9993 0.9979 0.9990 0.9993 0.9950 0.9983 –
0.9999 0.9996 0.9998 0.9995 0.9998 0.9998
0.9998 0.9991
Spike level (μg kg−1)
97 ± 9 97 ± 14 101 ± 10 93 ± 16 101 ± 9 89 ± 12 114 ± 15 73 ± 17 91 ± 13 98 ± 19 79 ± 9 97 ± 8 92 ± 5 94 ± 6 99 ± 11 – 96 ± 6 89 ± 7 100 ± 8 94 ± 5 87 ± 20 104 ± 6 – 85 ± 18 105 ± 12 106 ± 20 98 ± 10 102 ± 7 97 ± 13 91 ± 11
−27 56 −11 8 4 68 −5
91 ± 9 94 ± 8 99 ± 4 86 ± 16 94 ± 6 99 ± 6
−21 −16 218 196 −15 −12 2 −8 −7 −13 2 6 5 −13 −18 −31 −29 −5 −13 −6 −4 – −16 −15 0 −3 63 −3 –
57 ± 6 86 ± 12
88 ± 11 97 ± 5 100 ± 12 90 ± 7 96 ± 11 75 ± 7 78 ± 4
87 ± 3 84 ± 4 84 ± 6 85 ± 6 86 ± 2 79 ± 3 83 ± 13 76 ± 8 87 ± 4 81 ± 6 77 ± 3 83 ± 3 88 ± 4 84 ± 2 86 ± 4 – 80 ± 3 89 ± 12 80 ± 1 90 ± 8 71 ± 14
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