Mechanochemistry of Lignocellulosic Materials

Mechanochemical reactions of lignocellulosic materials, namely wood, wood cellulose, cotton and lignin, were studied using mechanical milling systems. Mechanical energy supplied by compression and shear forces in milling was sufficient to change the topoc

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CONTENTS OF VOLUMES 5 AND 6 Volume 5

Degradation Studies Involving Analysis by a Differential Distillation Technique. W. J. MCGILL

The Thermal Degradation of Poly-a-Esters. B. J. TIGHE Degradation and Stabilisation of Polyesters. H. ZIMMERMANN Acid-Catalysed Photoreactions: Photolytic Behaviour of Polyamides Containing Truxillic and Truxinic Units. G. MONTAUDo and E. SCAMPORRINO Oxidation of Polymers and Associated Thermally Stimulated Current. H. AOKI and T. SUZUKI

Low Temperature Oxidation of Solid Polypropylene. V. A. ROGINSKY Index Volume 6

The Evolution of Hydrogen Fluoride from Hydrofiuoro-Elastomers. W. W. WRIGHT Radiation Degradation of Poly(Olefin Sulphone)s-Fundamental Research to Practical Applications. MURRAE J. BOWDEN and JAMES H. O'DONNELL Polymer Stability in Aggressive Media. G. E. ZAIKOV Characterisation of Oxidised Polyolefines by Reaction with Sulphur Dioxide. T. J. HENMAN

Degradation of Virgin and Modified Chlorine Containing Polymers. F. TCrnos, B. IvAN, T. KELEN and J. P. KENNEDY Kinetics and Mechanism of the Oxidation of Stressed Polymer. N. Y A. RApOPORT and G. E. ZAIKOV Index

DEVELOPMENTS IN

POLYMER DEGRADATION-7

Edited by

N. GRASSIE Chemistry Department, The University, Glasgow, UK

ELSEVIER APPLIED SCIENCE LONDON and NEW YORK

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© ELSEVIER APPLIED SCIENCE PUBLISHERS LTD 1987 Softcover reprint of the hardcover I st edition 1987 British Library Cataloguing in Publication Data Developments in polymer degradation7 1. Polymers and polymerizationDeterioration 668.9 QD381.8 The Library of Congress has cataloged this work as follows: Developments in polymer degradation.-1- -London: Applied Science Publishers, c1977v. : ill.; 23 cm.-(Developments series) Includes bibliographies and index. 1. Polymers and polynierization-Deterioration-Collected works. Series 668.~c19 84-643156 QD381.8D483

I.

ISBN-13: 978-94-010-8032-3 e-ISBN-13: 978-94-009-3425-2 DOl: 10.1007/978-94-009-3425-2

The selection and presentation of material and the opinions expressed are the sole responsibility of the author(s) concerned. Special regulations for readers in the USA This publication has been registered with the Copyright Clearance Center Inc. (CCC), Salem, Massachusetts. Information can be obtained from the CCC about conditions under which photocopies of parts of this publication may be made in the USA. All other copyright questions, including photocopying outside of the USA, should be referred to the publisher. All rights reserved. No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, or otherwise, without the prior written permission of the publisher.

PREFACE

The purpose of this volume, like that of its predecessors in the series, is to pr