Modern Aspects of Electrochemistry No. 12
The first chapter in the present volume takes up a well-known theme in modern context: the ideas concerning non-Stokesian mechanisms of ion transport. We are happy that one of the great pioneers of modern electrochemistry, T. Erdey-Gniz, in collaboration
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LIST OF CONTRIBUTORS A. COVINGTON Department of Chemistry University of Newcastle Newcastle, England T. ERDEY-GRUZ The Academy of Science Budapest, Hungary J.-P. FARGES Department of Biochemistry University of Nice Nice, France F. GUTMANN Department of Chemistry Macquarie University Sydney, Australia M.A. HABIB School of Physical Sciences The Flinders University of South Australia Adelaide, Australia K.A. KINOSHITA United Technologies Incorporated Middletown, Connecticut S. LENGYEL The Academy of Science Budapest, Hungary K.E. NEWMAN Department of Chemistry University of Keele Keele Park Staffs, England P. STONEHART United Technologies Incorporated, Middletown, Connecticut A Continuation Order Plan is available for this series. A continuation order will bring delivery of each new volume immediately upon publication. Volumes are billed only upon actual shipment. For further information please contact the publisher.
MODERN ASPECTS OF ELECTROCHEMISTRY No. 12 Edited by
J. O'M. BOCKRIS School of Physical Sciences The Flinders University Adelaide, South Australia
and
B. E. CONWAY Department of Chemistry University of Ottawa Ottawa, Canada
PLENUM PRESS • NEW YORK AND LONDON
Library of Congress cataloged the first volume of this title as follows: Modern aspects of electrochemistry. no. [1] Washington, Butterworths, 1954v. illus. 23 cm. No. 1-2 issued as Modern aspects series of chemistry. Editors: no. 1- J. Bockris (with B. E. Conway, no. 3Imprint varies: no. 1, New York, Academic Press.-No. 2, London, Butterworths.
1. Electrochemistry-Collected works. ed. II. Conway, B. E. ed. pects series of chemistry) QD552.M6
I. Bockris, John O'M., (Series: Modern as54-12732 rev
Library of Congress Catalog Card Number 54-12732 ISBN 978-1-4615-7454-5 ISBN 978-1-4615-7452-1 (eBook) DOl 10.1007/978-1-4615-7452-1 © 1977 Plenum Press, New York Softcover reprint of the hardcover 1st edition 1977 A Division of Plenum Publishing Corporation 227 West 17th Street, New York, N. Y. 10011
All rights reserved No part of this book may be reproduced, stored in a retrieval system, or transmitted, in any form or by any means, electronic, mechanical, photocopying, microfilming, recording, or otherwise, without written permission from the Publisher
To A. N. Frumkin
Preface The first chapter in the present volume takes up a well-known theme in modern context: the ideas concerning non-Stokesian mechanisms of ion transport. We are happy that one of the great pioneers of modern electrochemistry, T. Erdey-Gniz, in collaboration with S. Lengyel, has consented to write this article for us. Along with it is a solution-oriented article in spectroscopic vein, namely, that by A. Covington and K. E. Newman on the analysis of solution constituents by means of nuclear magnetic resonance studies. Progress in the electrochemistry of the double layer has perked up, and the advances have been triggered from critical experiments, one showing that fluoride ions are specifically adsorbed, and the other showing that the position of maximum disorder of the wate
