Modern Aspects of Electrochemistry Volume 28

No. 28 of this highly regarded series explores the fundamental and applied aspects of electrochemical science. This volume features two detailed studies on the rapidly developing field of electrochemical surface science.

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No. 28

LIST OF CONTRIBUTORS A. J. ARVIA

R.C. SAL VAREZZA

Instituto de Investigaciones Fisicoquimicas Te6ricas y Aplicadas Universidad Nacional de La Plata (I 900) La Plata, Argentina

Instituto de Investigaciones Fisicoquimicas Te6ricas y Aplicadas Universidad Nacional de La Plata (I 900) La Plata, Argentina

MANFRED W. BREITER

MANUEL P. SORIAGA

Institute of Technical Electrochemistry Technical University of Vienna A-I060 Vienna, Austria

Department of Chemistry Texas A&M University College Station, Texas 77843

S. G. CHRISTOV

JOHN L. STICKNEY

Bulgarian Academy of Sciences Institute of Physical Chemistry Sofia 1040, Bulgaria

Department of Chemistry University of Georgia Athens, Georgia 30602

C. GUTIERREZ

ANDRZEJ WIECKOWSKI

Instituto de Quimica Fisica "Rocasolano," Consejo Superior de Investigaciones Cientificas Madrid-28006, Spain

Department of Chemistry University of Illinois Urbana, Illinois 61801

DAVID A. HARRINGTON Department of Chemistry University of Victoria Victoria, British Columbia Canada, V8W 2Y2

WOLFGANG J. LORENZ Institute of Physical Chemistry University of Karlsruhe D-76l3l Karlsruhe, Germany

GEORG SAEMANN-ISCHENKO Institute of Physics University of Erlangen-Nuremberg D-91058 Erlangen, Germany A Continuation Order Plan is available for this series. A continuation order will bring delivery of each new volume immediately upon publication. Volumes are billed only upon actual shipment. For further information please contact the publisher.

MODERN ASPECTS OF ELECTROCHEMISTRY No. 28 Edited by

B.E. CONWAY University of Ottawa Ottawa, Ontario, Canada

J. O'M. BOCKRIS Texas A&M University College Station, Texas

and

RALPH E. WHITE University of South Carolina Columbia, South Carolina

SPRINGER SCIENCE+BUSINESS MEDIA, LLC

The Library of Congress cataloged the first volume of this title as follows: Modern aspects of electrochemistry, no. [1] Washington Butterworths, 1954— v. illus., 23 cm. No. 1—2 issued as Modern aspects series of chemistry. Editors: no 1- J. Bockris (with B. E. Conway, No. 3 - ) Imprint varies: no. 1, New York, Academic Press.—No. 2, London, Butterworths. 1. Electrochemistry—Collected works. I. Bockris, John O'M.ed. II. Conway, B.E. ed. (Series: Modern aspects series of chemistry) QD552.M6 54-12732 rev

ISBN 978-1-4899-1720-1 DOI 10.1007/978-1-4899-1718-8

ISBN 978-1-4899-1718-8 (eBook)

© Springer Science+Business Media New York 1996 Originally published by Plenum Press, New York in 1996 Softcover reprint of the hardcover 1st edition 1996 1098765432 1 AU rights reserved No part of this book may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, microfilming, recording, or otherwise, without written permission from the Publisher

Preface The present volume comprises five chapters covering topics having relevance both in fundamental and in applied aspects of the field of electrochemical science. On the fundamental side, two of the contributions are concerned with the currently very active area of