Syntheses of Fluoroorganic Compounds
Recently there has been a tremendous growth in the chemistry of fluoroorganic compounds, which find wide applicatiori in various fields of technique and are used to solve some basic theoretical problems. The chemical properties of these compounds are rath
- PDF / 71,741,606 Bytes
- 307 Pages / 481.89 x 691.654 pts Page_size
- 45 Downloads / 208 Views
Springer-¥edag Berlin Heidelberg New York Tokyo 1985
Professor I. L. Knunyants Professor G. G. Yakobson
t
Institute of Organic Chemistry, SU-630090 Novosibirsk
ISBN-13: 978-3-642-70209-9 e-ISBN-13: 978-3-642-70207-5 DOl: 10.1007/978-3-642-70207-5 Library of Congress Cataloging in Publication Data. Main entry under title: Syntheses of fluoroorganic compounds. Bibliography: p. Includes index. 1. Organofluoron compounds. 2. Chemistry, Organic-Synthesis. I. Knunyants, Ivan Ludvigovich. II. Yakobson, G. G. (Georgi Gustavovich) 547'.02 84-26875 QD412.FIS95 1985 This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, specifically those of translation, reprinting, re-use of illustrations, broadcasting, reproduction by photocopying machine or similar means, and storage in data banks. Under § 54 of the German Copyright Law where copies are made for other than private use, a fee is payable to 'Verwertungsgesellschaft Wort', Munich.
© Springer-Verlag Berlin, Heidelberg 1985 Softcover reprint of the hardcover 1st edition 1985 The use of registered names, trademarks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. Product Liability: The publisher can give no guarantee for information about drug dosage and application thereof contained in this book. In every individual case the respective user must check its accuracy by consulting other pharmaceutical literature.
2131/3020-543210
Preface
Recently there has been a tremendous growth in the chemistry of fluoroorganic compounds, which find wide applicatiori in various fields of technique and are used to solve some basic theoretical problems. The chemical properties of these compounds are rather specific, as well as the methods for their preparation. We realized that no good handbooks on the preparation offluoroorganic compounds were available, whereas the methods of preparation are scattered in numerous scientific papers and patents. Even such a well-known publication as Organic Syntheses contains just a few methods of preparation of fluoroorganic compounds. As a consequence, not only for newcomers but even for specialists, searching for simple and convenient methods for the preparation of the required compounds is tedious. To alleviate the problem, we undertook to prepare this book, which presents detailed preparation methods of more than 300 flu oro organic compounds. Emphasis has been laid on syntheses of polyfluorinated compounds, since they are of major interest with respect to preparation and utility. Preparation of fluoroorganic compounds is based both on the classical methods of organic chemistry and on the specific ones, which is due to the difficulty or even impossibility of the direct introduction of fluorine into a definite position of organic molecule. Most organic compounds of fluorine are prepared by a succession of conversions of a relatively small nu
