Surface Coatings Vol I-Raw Materials and Their Usage

Arising from an examination in 1969 of the education and trammg opportumtles for paint industry technicians, it was recognized that the various courses available at that time did not fully serve their needs. While a few large companies had developed in-ho

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Prepared by the Oil and Colour Chemists' Association, Aus1ralia

Springer-Science+Business Media, B.V.

© Springer Science+ Business Media Dordrecht 1983 Originally published by Chapman and Hall Ltd in 1983 Softcover reprint of the hardcover 1st edition 1983

ISBN 978-94-011-6942-4 DOI 10.1007/978-94-011-6940-0

ISBN 978-94-011-6940-0 (eBook)

All rights reserved. No part ofthis book may be reprinted, or reproduced or utilized in any form or by any electronic, mechanical or other means, now known or hereafter invented, including photocopying and recording, or in any information storage or retrieval system, without permission in writing from the publisher.

Those mernbers oJ OCCAA who have contributed to this book could not have done so without the understanding,Jorbearance, advice and encouragement if their companies, colleagues andJamilies, and it is to thern that we dedicate this work.

TEXTBOOK COMMITTEE MEMBERS

J M Waldie

Chairman; editorial revision D D Bonney Biographies R Drummond Editorial revision JA Foxton Editorial revision K Freeman Technical W W Gallagher Technical; major reviews J HaIe Technical D S Howie N S W Universiry Press G Liepins Index preparation BJ Lourey Technical DM D Stewart Technical R E Walton Editorial revision I R Waples SI units RJ Willis Technical; Chairman, Technical Education Sub-committee

CONTENTS I 2 3 4 5 6 7 8 9 10 lI 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30

Foreword Priface The Past, Present and Future of the Surface Coatings Industry Introduction to Polymer Science Vegetable Oils Oleoresinous Media Alkyd Resin Technology Manufacture of Alkyd Resins Applications of Alkyd Resins Polyesters Amino Resins Phenolic Resins Polyurethane Resins Epoxy Resins Water Dispersible Epoxy Coatings Silicone Resins Acrylic Solution Resins Emulsion Polymerization Theory Emulsion Properties I: Effect of Monomer Composition Emulsion Properties 2: Effect ofWater Phase and Particle Size Emulsion Proper ti es 3: Film Formation Emulsion Polymers: Manufacture and Testing Applications ofEmulsion Polymers Water-Reducible Resins Water-Soluble Polymers Solvents Inorganic Pigments Titanium Dioxide Pigments Organic Pigments Extender Pigments Paint Driers Paint Additives Contributors and Reviewers Appendix: Useful Data and Conversion Tables Index v

UZ UZt

I

4 20

45

53 65 75

78 87

99 105 120 130 134 144

158 164 171

175 184 194 208 244 257 288 305 313 344 352 362

378 380 399

FOREWORD Arising from an examination in 1969 of the education and trammg opportumtles for paint industry technicians, it was recognized that the various courses available at that time did not fully serve their needs. While a few large companies had developed in-house training arrangements, the many medium and smaller fi.rms in the raw material supply, paint manufacturing or paint user industries, were unable to provide their own comprehensive training programs. With a view to improving this situation, an advisory committee comprising ofrepresentatives of the Australian Paint Manufacturers' Federation and