Modern Aspects of Electrochemistry
This volume of Modern Aspects contains seven chapters. The major topics covered in the first six chapters of this volume include fundamentals of solid state electrochemistry; kinetics of electrochemical hydrogen entry into metals and alloys; oxidation of
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Modern Aspects of Electrochemistry, No. 36:
• The study of electrochemical nuclear magnetic resonance (EC-NMR); in situ both sides of the electrochemical interface via the simultaneous use of I3C and 193Pt NMR. • Recent impressive advances in the use of rigorous ab initio quantum chemical calculations in electrochemistry. • Fundamentals of ab initio calculations, including density functional theory (DFf) methods, help to understand several key aspects of fuel cell electrocatalysis at the molecular level. • The development of the most important macroscopic and statistical thermodynamic models that describe adsorption phenomena on electrodes. • Electrochemical promotion and recent advances of novel monolithic designs for practical utilization. • New methods for CT analysis and an explanation for the existing discrepancy in Li diffusivity values obtained by the diffusion control CT analysis and other methods. Modern Aspects of Electrochemistry, No. 35:
• Impedance spectroscopy with specific applications to electrode processes involving hydrogen. • Fundamentals and contemporary applications of electroless metal deposition. • The development of computational electrochemistry and its application to electrochemical kinetics. • Transition of properties of molten salts to those of aqueous solutions. • Limitations of the Born Theory in applications to solvent polarization by ions and its extensions to treatment of kinetics of ionic reactions.
LIST OF CONTRIBUTORS M. ABRAHAM
GYORGY F6TJ
Chemistry Department University of Montreal Montreal, Quebec, Canada
Unit of Electrochemical Engineering, Institute of Chemical and Biological Process Science School of Basic Sciences, Swiss Federal Institute of Technology CH-1015 Lausanne, Switzerland
M.-C. ABRAHAM Chemistry Department University of Montreal Montreal, Quebec, Canada
FAISAL M. AL-FAQEER
K. HEMMES
Saudi Aramco E-7600 Dhahran 31311, Saudi Arabia
Fac Technology Policy and Management of TUDeift Jaffalaan 5 2628 BX DELFf The Netherlands
C. L. BRIANT Division of Engineering Brown University 182 Hope Street, Box D Providence, RI 02912, USA
CHRISTOS COMNINELLIS Unit of Electrochemical Engineering Institute of Chemical and Biological Process Science School of Basic Sciences, Swiss Federal Institute of Technology CH-1015 Lausanne, Switzerland
HOWARD W. PICKERING Department of Materials Science and Engineering Pennsylvania State University University Park, PA 16802
ZOLTAN NAGY Argonne National Laboratory Materials Science Division Argonne, Illinois, 60439, USA
A Continuation Order Plan is available for this series. A continuation order will bring delivery of each new volume immediately upon publication. Volumes are billed only upon actual shipment. For further information please contact the publisher.
MODERN ASPECTS OF ELECTROCHEMISTRY No.37 Edited by
RALPH E. WHITE University of South Carolina Columbia, South Carolina
B. E. CONWAY University of Ottawa Ottawa, Omario, Canada
C.G.VAYENAS University al' Patras Putras, Gree('e
and