The Iodine Molecule Insights into Intra- and Intermolecular Perturba
This book presents experimental and theoretical spectroscopic studies performed over the last 25 years on the iodine molecule’s excited states and their perturbations. It is going to be of interest to researchers who study intra- and intermolecular pertur
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Iodine Molecule
Insights into Intra- and Intermolecular Perturbation in Diatomic Molecules
The Iodine Molecule
Sergey Lukashov • Alexander Petrov • Anatoly Pravilov
The Iodine Molecule Insights into Intra- and Intermolecular Perturbation in Diatomic Molecules
Sergey Lukashov Department of Physics Saint Petersburg State University Saint Petersburg, Russia
Alexander Petrov Department of Physics Saint Petersburg State University Saint Petersburg, Russia
Anatoly Pravilov Department of Physics Saint Petersburg State University Saint Petersburg, Russia
National Research Centre “Kurchatov Institute”, B.P. Konstantinov Petersburg, Nuclear Physics Institute Gatchina, Leningrad district, Russia
ISBN 978-3-319-70071-7 ISBN 978-3-319-70072-4 https://doi.org/10.1007/978-3-319-70072-4
(eBook)
Library of Congress Control Number: 2017960170 © Springer International Publishing AG 2018 This work is subject to copyright. All rights are reserved by the Publisher, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission or information storage and retrieval, electronic adaptation, computer software, or by similar or dissimilar methodology now known or hereafter developed. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. The publisher, the authors and the editors are safe to assume that the advice and information in this book are believed to be true and accurate at the date of publication. Neither the publisher nor the authors or the editors give a warranty, express or implied, with respect to the material contained herein or for any errors or omissions that may have been made. The publisher remains neutral with regard to jurisdictional claims in published maps and institutional affiliations. Printed on acid-free paper This Springer imprint is published by Springer Nature The registered company is Springer International Publishing AG The registered company address is: Gewerbestrasse 11, 6330 Cham, Switzerland
Preface
Methods of theoretical and experimental studies of spectroscopic characteristics of the iodine molecule valence, ion-pair (IP) and Rydberg states, spectroscopic characteristics themselves, nonadiabatic perturbations of these states, and RgI2 van der Waals (vdW) complexes as well as collision-induced processes are reviewed in the book. The emphasis of the book is focused on nonadiabatic perturbation in a free molecule, and intermolecular nonadiabatic perturbation occurred in collisioninduced nonadiabatic transitions and RgI2 vdW complexes. Spectroscopic characteristics as well as population and decay of the RgI2 excited states are analyzed. The principal features of intermolecular perturbations which manifest
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