The Jahn-Teller Effect Fundamentals and Implications for Physics and

The Jahn-Teller effect continues to be a paradigm for structural instabilities and dynamical processes in molecules and in the condensed phase. Among the many important newer developments in the field one should mention cooperative phenomena in cryst

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chemical physics

97

Springer Series in

chemical physics Series Editors: A. W. Castleman, Jr. J. P. Toennies K. Yamanouchi W. Zinth The purpose of this series is to provide comprehensive up-to-date monographs in both well established disciplines and emerging research areas within the broad f ields of chemical physics and physical chemistry. The books deal with both fundamental science and applications, and may have either a theoretical or an experimental emphasis. They are aimed primarily at researchers and graduate students in chemical physics and related f ields.

For further volumes: http://www.springer.com/series/676

Horst Köppel David R. Yarkony Heinz Barentzen (Eds.)

The Jahn-Teller Effect Fundamentals and Implications for Physics and Chemistry With 350 Figures

123

Professor Horst Köppel

Professor Heinz Barentzen

Universität Heidelberg Theoretische Chemie Im Neuenheimer Feld 229 69120 Heidelberg Germany E-Mail: [email protected]

MPI für Festkörperforschung Heisenbergstr. 1 70569 Stuttgart Germany E-mail: [email protected]

Professor David R. Yarkony Johns Hopkins University Department of Chemistry 3400 N. Charles Street Baltimore MD 21218 USA E-Mail: [email protected]

Series Editors:

Professor A.W. Castleman, Jr. Department of Chemistry, The Pennsylvania State University 152 Davey Laboratory, University Park, PA 16802, USA

Professor J.P. Toennies Max-Planck-Institut f¨ur Str¨omungsforschung Bunsenstrasse 10, 37073 G¨ottingen, Germany

Professor K. Yamanouchi University of Tokyo, Department of Chemistry Hongo 7-3-1, 113-0033 Tokyo, Japan

Professor W. Zinth Universit¨at M¨unchen, Institut f¨ur Medizinische Optik ¨ Ottingerstr. 67, 80538 M¨unchen, Germany

ISSN 0172-6218 ISBN 978-3-642-03431-2 e-ISBN 978-3-642-03432-9 DOI 10.1007/978-3-642-03432-9 Springer Heidelberg Dordrecht London New York Library of Congress Control Number: 2009938946 © Springer-Verlag Berlin Heidelberg 2009 This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilm or in any other way, and storage in data banks. Duplication of this publication or parts thereof is permitted only under the provisions of the German Copyright Law of September 9, 1965, in its current version, and permission for use must always be obtained from Springer. Violations are liable to prosecution under the German Copyright Law. The use of general descriptive names, registered names, trademarks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. Cover design: SPi Publisher Services Printed on acid-free paper Springer is part of Springer Science+Business Media (www.springer.com)

Preface

The Jahn–Teller (JT) effect continues to be a paradigm for structural instabilities and dynamical processes in molecules