Two-Dimensional Black Phosphorus Nanomaterials: Emerging Advances in Electrochemical Energy Storage Science
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REVIEW
Cite as Nano-Micro Lett. (2020) 12:179 Received: 23 May 2020 Accepted: 23 July 2020 © The Author(s) 2020
https://doi.org/10.1007/s40820-020-00510-5
Two‑Dimensional Black Phosphorus Nanomaterials: Emerging Advances in Electrochemical Energy Storage Science Junye Cheng1,3, Lingfeng Gao2, Tian Li3, Shan Mei4, Cong Wang2, Bo Wen2, Weichun Huang5, Chao Li2, Guangping Zheng3, Hao Wang1 *, Han Zhang2 * Junye Cheng, Lingfeng Gao and Tian Li have contributed equally to this work. * Hao Wang, [email protected]; Han Zhang, [email protected] Guangdong Provincial Key Laboratory of Micro/Nano Optomechatronics Engineering, College of Mechatronics and Control Engineering, Shenzhen University, Shenzhen 518060, People’s Republic of China
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Collaborative Innovation Center for Optoelectronic Science and Technology, International Collaborative Laboratory of 2D Materials for Optoelectronic Science and Technology of Ministry of Education and Guangdong Province, Shenzhen University, Shenzhen 518060, People’s Republic of China Department of Mechanical Engineering, Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong, People’s Republic of China Department of Materials Science and Engineering, Drexel University, Philadelphia, PA 19104, USA Nantong Key Lab of Intelligent and New Energy Materials, College of Chemistry and Chemical Engineering, Nantong University, Nantong 226019, Jiangsu, People’s Republic of China
HIGHLIGHTS • Two-dimensional black phosphorus (2D BP) possesses huge potential in electrochemical energy storage field owing to its unique electronic structure, high charge carrier mobility, and large interlayer spacing. • Comparison on the different preparation methods and processes, characteristics, and applications of few-layer BP is presented. • The applications of 2D BP in electrochemical energy storage devices in these years are well reviewed.
ABSTRACT Two-dimensional black phosphorus (2D BP), well known as phosphorene, has triggered
on 2D BP, a timely review on this topic is in demand to further extend the application of 2D BP in energy storage. In this review, recent advances in experimental and theoretical development of 2D BP are presented along with its structures, properties, and synthetic methods. Particularly, their emerging applica-
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2D Black Phosphorus
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the performance of energy storage devices. With the rapid development of energy storage devices based
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cal specific capacity, 2D BP has been widely studied as electrode materials and significantly enhanced
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energy storage, sensor, etc. Owing to the large surface area, good electric conductivity, and high theoreti-
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2D BP intriguing properties, which facilitate its potential applications in various fields, such as catalyst,
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tremendous attention since the first discovery in 2014. The unique puckered monolayer structure endows
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tions in electrochemical energy storage, including Li−/K−/Mg−/Na-ion, Li–S batteries, and supercapacitors, are systematically summarized wi
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