Hydrogeochemical Assessment of Groundwater for Drinking and Agricultural Use: A Case Study of Rural Areas of Alwar, Raja

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Hydrogeochemical Assessment of Groundwater for Drinking and Agricultural Use: A Case Study of Rural Areas of Alwar, Rajasthan Ankur Aggarwal

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Jigyasa Soni1 Khyati Sharma1 Mohnish Sapra1 Chitrakshi1 Oznur Karaca2 A. K. Haritash1 ●









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Received: 6 April 2020 / Accepted: 5 September 2020 © Springer Science+Business Media, LLC, part of Springer Nature 2020

Abstract Groundwater contributes substantially to the development of arid and semi-arid regions around the globe. The present study integrates groundwater quality and its suitability for drinking and irrigation around Alwar city of Rajasthan state, where agriculture is the major land use. The application for drinking was assessed by comparing the observed value with prescribed standards of WHO. Groundwater was found suitable for drinking at most of the locations. The suitability of groundwater for irrigation was determined by calculating ion-based ratios and comparing them against the suggested ratios and indices for agricultural quality. Suitability for irrigation was assessed against electrical conductivity (EC), percentage sodium (%Na), residual Na2CO3 (RSC), per cent soluble sodium (SSP), sodium adsorption ratio (SAR), Mg hazard and permeability index (PI) etc., and the quality was compromised for EC, %Na and Mg Hz. Since the soil was sandy, the groundwater was found suitable for irrigation over long-term use, with the only problem of magnesium hazard. Based on the different ratios of anions and cations, silicate weathering was observed to be regulating groundwater chemistry, and the groundwater belonged to mixed CaMgCl and CaHCO3− type based on Piper’s classification and relative abundance of ions. Further, meteoric genesis classification showed that the groundwater in the study region had direct base exchange and shallow meteoric water percolation. Presence of kaolinite and quartz minerals in soil confirmed that silicate weathering is the major process controlling groundwater chemistry. Keywords Siliserh Lake Groundwater Irrigation Silicate weathering FTIR ●





Introduction Groundwater is the source of daily water supply to about 3.0 billion people worldwide. Of the total groundwater extraction globally, about 40% is used in agriculture (Haritash et al. 2017; Kumar et al. 2017). Agriculture is a major economic sector in India contributing to 46% of the gross national product (Kumarasamy et al. 2011). Since the advent of intensive agriculture, the pressure on groundwater has increased to meet the demand for irrigation. As a result, the groundwater table in many regions in India is receding, and issues of water quality have emerged particularly in water-scarce regions. Groundwater plays an important role

* A. K. Haritash [email protected] 1

Department of Environmental Engineering, Delhi Technological University, Delhi 110042, India

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Department of Geological Engineering, Çanakkale Onsekiz Mart Üniversity, Canakkale, Turkey



in agricultural and industrial production around the globe, and about 90% of the

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