Modern Aspects of Electrochemistry Volume 29
No. 29 offers new insights into the energies of activation of electrode reactions and the interfacial behavior of proteins.
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LIST OF CONTRIBUTORS SYMEON I. BEBELIS Department of Chemical Engineering University ofPatras Patras GR-26500, Greece MILAN M. JAKSIC Department of Chemical Engineering University ofPatras Patras GR-26500, Greece STYLIANOS G. NEOPHYTIDES Department of Chemical Engineering University ofPatras Patras GR-26500, Greece ILEANA-HANIA PLONSKI Institute of Atomic Physics IFTM RO-76900 Bucharest, Romania
SHARON G. ROSCOE Department of Chemistry Acadia University Wolfville, Nova Scotia, Canada BOP lXO
DARKO B. SEP A Faculty of Technology and Metallurgy University of Belgrade 11000 Belgrade, Yugoslavia CONSTANTIN OS G. VAYENAS Department of Chemical Engineering University ofPatras Patras GR-26500, Greece RONALD WOODS CSIRO Division of Minerals Port Melbourne, Victoria 3207, Australia
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MODERN ASPECTS OF ELECTROCHEMISTRY No. 29 Edited by
J. O'M. BOCKRIS Texas A&M University College Station. Texas
B.E. CONWAY University of Ottawa Ottawa. Ontario. Canada
and
RALPH E. WHITE University of South Carolina Columbia. South Carolina
PLENUM PRESS • NEW YORK AND LONDON
The Library of Congress cataloged the first volume of this title as follows: Modern aspects of electrochemistry. no. [I] Washington Butterworths, 1954v. illus., 23 cm. No. 1-2 issued as Modern aspects series of chemistry. Editors: no 1- J. Bockris (with B. E. Conway, No. 3- ) Imprint varies: no. I, New York, Academic Press.-No. 2, London, Butterworths. I. Electrochemistry--Collected works. I. Bockris, John O'M.ed. II. Conway, B.E. ed. (Series: Modern aspects series of chemistry) QD552.M6
54-12732 rev
ISBN -13:978-1-4613-7999-7 e-ISBN -13:978-1-4613-0327-5 DOl: 10.1007/978-1-4613-0327-5 © 1996 Plenum Press, New York Softcover reprint of the hardcover 1st edition 1996
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Preface MODERN ASPECTS OF ELECTROCHEMISTRY VOLUME 29 This volume of Modern Aspects contains a remarkable spread of interests. In respect to the first, Dr. Darko Sepa takes up a much discussed subjecthow does one evaluate the fundamental quantity, energy of activation? He deals with this in very considerable detail and allows us to see the various pitfalls which pertain to the evaluation, particularly those that arise as a consequence of the variation of the symmetry factor with temperature. One of the more remarkable advances in electrochemistry since 1950 is described by Vayenas et al. It is the effect of electrical potential changes on catalyst surfaces. The subject-though only a few years old-is fully d
